
Prof. Zhihui Shao
Yunnan University, China
Title: From Chiral Primary Amine Catalysis to Secondary Amine Catalysis: Diastereodivergence & Enantiodivergence
Abstract:
Asymmetric aminocatalysis has been established a powerful tool to functionalize
the carbonyl compounds. In this
talk, we will discuss the discovery and development of chiral primary amine
catalysts and chiral acyclic secondary amine catalysts to address some
difficult reactions. In particular, we will discuss the diastereodivergence between chiral
primary amine catalysis and secondary amine catalysis, and the enantiodivergence
between chiral cyclic secondary amine catalysis and acyclic secondary amine catalysis.
Biography:
Zhihui Shao obtained his PhD from Lanzhou University in 2004. He carried
out his postdoctoral studies with Professor Stephen Hanessian at University of
Montreal (2004–2006), and with Professor Albert, S. C. Chan at The Hong Kong
Polytechnic University (2006–2007), respectively. Then he joined the faculty of
the School of Chemical Science and Technology at Yunnan University, where he
began independent research. Now he is a professor and vice dean of School of
Chemical Science and Technology, Yunnan University. His research interests
focus on asymmetric catalysis and synthesis.