Circularly polarized luminescence (CPL) has special polarization state and angular momentum, and has application prospects in many frontier fields such as quantum computing and 3D stereoscopic display. However, the reported materials do not own both high magnetic transition dipole moment and electric transition dipole moment simultaneously, resulting in low CPL intensity and asymmetry factor. Besides，white CPL is hard to realize. Therefore, it is a challenging issue that how to obtain efficient CPL system and realize the regulation and improvement of CPL performance in CPL field. In this project, chiral monoamines and diamines with different steric effect and configurations are designed to construct 0D-2D perovskite with high CD intensity. The low dimension and crystal plane orientation and structural distortion regulated by hydrogen bond, together lead to broadband self-trapping effect based CPL. Some of the chiral crystals show second harmonic generation due to the chiral space group, i.e. non-centrosymmetric crystal structure.

Shuang Jiang received her B.S. and Ph.D. degrees in chemical engineering from Tianjin, China, in 2011 and 2017, respectively. From November 2014 to November 2016, she was a visiting scholar under the supervision of Prof. Nicholas Kotov at the University of Michigan, USA. Currently, she is an associate professor at Tianjin University, China. Her research interests focus on chiral semiconductor nanomaterials, including their chiral optical properties such as circular dichroism, circularly polarized luminescence, and second harmonic generation. Shuang has published over 70 journal papers and conference proceedings and delivered more than 10 invited presentations at academic conferences. She has filed 13 patents, with eight already granted. Additionally, she serves as a member of the Youth Editorial Board for SmartMat, Journal of Analysis and Testing, and Advanced Powder Materials. She serves as the guest editor for 4 journals and reviewer for more than 20 journals.