High theoretical capacity and low discharge platforms of Sn and Sb-based materials are an auspicious anode material for sodium ion batteries. Although, their large volume change before and after sodium insertion during cycling leads to unstable electrode structure and poor cycle performance. In view of the above, a thermo che[1]mical strategy by a simple one-pot for producing 3–6 nm diameter homogeneously dispersed Sn/SnSb nano[1]particles on a nitrogen-doped graphene sheet with a large-scale and low-cost feature for high performance sodium ion battery is reported. Highly dispersed nano Sn-SnSb alloy/graphene composite electrode not only had good stress adaptability and good integrity protection to prevent agglomeration and polarization during cycling, and also provided the rapid Na+ diffusion and electronic transfer channels, thus showing high rate and ultra stable cycle performance. The as-prepared electrode could maintain the super stable reversible capacities of 251.8, 146.2 and 60.2 mAh g−1 at 1, 4 and 10 A g−1 over 1000 cycles, respectively.