Prof.  AHMAD ZUHAIRI  ABDULLAH
School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus,  Malaysia

Title: Role of pore geometry of Ca1+xAl1-xLaxO3 composite catalyst supported on MCM-41 in selective glycerol etherification to lower molecular weight polyglycerols as potential oxygenated fuel additives

Abstract:

Glycerol is abundantly produced by biodiesel as well as other downstream oleochemical industries and its industrial uses are rather limited to the extent that it is regarded as a waste to be managed. Polyglycerols have high potential to be used as an oxygenated additives in fuel in which they are compounds that contain oxygen to be blended with fuels to improve combustion efficiency and reduce emissions. Especially diglycerol and triglycerol, they are potential products towards making fuels greener and also of industrial importance in many other applications. However, selective production of through catalytic means often subject to a few drawbacks. A novel heterogeneous catalyst was prepared by means of a co-precipitation method and its activity in selective glycerol etherification was demonstrated. Lanthanum (La):calcium (Ca) ratio, temperature, and the duration of calcination positively influenced the conversion of glycerol. A regression model was established to predict the effect of calcination conditions and La:Ca ratio on glycerol conversion. After 8 h of reaction, a conversion of 81.6 % was achieved under atmospheric pressure at 250 °C, 3.5 wt. % of catalyst and with a La to Ca ratio of 1:2.7. The catalyst was subjected to a thermal treatment at 560 °C for 4.5 h. The catalyst characterization revealed well-mixed oxides with desirable properties such as sufficient porosity and surface area. It also showed that the formation of the O–Ca–O functional group sitting on the surface of the catalyst facilitated high glycerol conversion. The synthesized catalyst with excellent porosity and stability area was promising for glycerol etherification.

Biography:

Professor Dr Ahmad Zuhairi Abdullah received his B. Tech (Hons), MSc, and PhD in 1995, 2000, and 2004, respectively. He was the Deputy Dean (Industry and Community Network) at the School of Chemical Engineering, Universiti Sains Malaysia between 2010-2012 and Deputy Dean (Research and Postgraduate Studies) between 2013-2018. He is also serving his deanship of the school in 2022-2024. He is registered as a Fellow of Akademi Sains Malaysia, a Professional Technologist at Malaysian Board of Technologists (MBOT), a Fellow of Institut Kimia Malaysia (IKM) and a Life member of the Malaysian Oil Scientists and Technologists’ Association (MOSTA). He is regularly appointed as an MBOT accreditation auditor and as a program’s external examiner for many academic programs in several Malaysian universities. His research works mostly involve the use of ordered porous catalytic materials in oleochemical reactions, renewable energy, waste treatment, and waste valorization. He has nearly 300 refereed publications in journals and book/book chapters mainly as the main author, and also involves as a technical committee member of nearly 150 international scientific conferences. He is often invited to share his research experiences at various international conferences held in Malaysia, Laos, Indonesia, Vietnam, Thailand, Pakistan, The Philippines, and PR China. In addition, he is an evaluator for research proposals from different ministries/agencies locally as well as from several international scientific bodies in the EU, USA, Oman, Qatar, Kazakhstan, and Chile. He is also an expert panel of the Department of Environment Malaysia for the evaluation of Environmental Impact Assessment reports for various proposed commercial projects related to petrochemical complexes, heavy oil facility, paper mills, metal smelting, chemical, lead-acid battery recycling plants, etc. He is one of the recipients of the Top Research Scientists Malaysia (TRSM) award in 2014 and was listed in the List of World’s Top 2% Scientists by Stanford University in 2020-2022. His h-index (Scopus) currently stands at 63more than 13,000 citations. He is a certified trainer with the Human Resource Development Corp (HRDC) of Malaysia.